Seem to have got to the bottom of this.
The basic cause is the accuracy of distributor Rotor phasing.
Even though I was running an after-market distributor, due to a number of factors, the quality of the product was not sufficient to avoid cross-fire when cranking.
So, the top tip of the day is: do not bother buying an MSD Digital 6 unless you are prepared to, or have the capability of, phasing the rotor; as 20 degrees is too much timing to pull out on cranking and cross-fire will result.
Save your money and run a 6AL variant, and use another device such as a manual retard box.
My fix was to chop up an MSD billet Distributor and weld it at the correct rotor phasing setting........MSD advise running a crank trigger with a Digital 6; and this is what I am doing with the Hemi

Pete Wiseman; Cambridge.
Mopar by the grace of God