Hi Steve, I had a similar problem with my rear drums and thought they would never budge
My adjusters were solid which in one way was a good thing as it meant the shoes were able to move back and clear of the drums ( but not good cos braking was poor

)
I spent the best part of a day with penetrating oil and a cow hide hammer and ended up leaving them soaked over night.
Next day with more persistent but moderate hammering

all round the rear edge they did eventually come off
I agree with the others that you must be as sure as sure can be that the adjusters and shoes are backed off to prevent any damage but it does sound very much like my issue, my drums were stuck/bonded on the inner faces.
This did take a lot of time and a couple of one ton bags of patience

but hang in there and I'm sure they will give in
I cleaned everything out (mask on and brake cleaner spray for the dust) and had to soak and dissassemble the adjusters to get them working, all worth it in the end.
I have some before and after pics, good luck mate and show them who's boss
